5'-Bromo-2'-hydroxyacetophenone, 98%
5'-Bromo-2'-hydroxyacetophenone, 98%
5'-Bromo-2'-hydroxyacetophenone, 98%
5'-Bromo-2'-hydroxyacetophenone, 98%
Thermo Scientific Chemicals

5'-Bromo-2'-hydroxyacetophenone, 98%

CAS: 1450-75-5 | C8H7BrO2 | 215.046 g/mol
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Catalog NumberQuantity
ALFH61979.1850 g
Catalog number ALFH61979.18
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Quantity:
50 g
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Specifications
Chemical Name or Material5'-Bromo-2'-hydroxyacetophenone
CAS1450-75-5
Health Hazard 1H315-H319-H335
Health Hazard 2GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Health Hazard 3P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c
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5?-Bromo-2?-hydroxyacetophenone (5-Bromo-2-hydroxyacetophenone) may be used in ligand in the preparation of tetrahedral metallocene complexes containing vanadium(IV), synthesis of {2?-[1-(5-bromo-2-oxidophenyl) ethylidene] benzohydrazidato (2-)} tris(pyridine) nickel(II)] pyridine solvate, synthesis of N?-[1-(5-bromo-2-hydroxyphenyl)ethylidene]-3,4,5-trihydroxybenzohydrazide dimethyl sulfoxide solvate trihydrate, preparation of 6-bromochromen-4-one.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
5′-Bromo-2′-hydroxyacetophenone (5-Bromo-2-hydroxyacetophenone) may be used in ligand in the preparation of tetrahedral metallocene complexes containing vanadium(IV), synthesis of {2′-[1-(5-bromo-2-oxidophenyl) ethylidene] benzohydrazidato (2-)} tris(pyridine) nickel(II)] pyridine solvate, synthesis of N′-[1-(5-bromo-2-hydroxyphenyl)ethylidene]-3,4,5-trihydroxybenzohydrazide dimethyl sulfoxide solvate trihydrate, preparation of 6-bromochromen-4-one.

Solubility
Soluble in Chloroform

Notes
Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.
RUO – Research Use Only

General References:

  1. R.A. Nyquist. The O-H out-of-plane deformation in intramolecularly hydrogen bonded phenols. Spectrochimica Acta. 1995, 19, (10), 1655-1664.
  2. Biswanath Das.; Katta Venkateswarlu.; Maddeboina Krishnaiah.; Harish Holla. An efficient, rapid and regioselective nuclear bromination of aromatics and heteroaromatics with NBS using sulfonic-acid-functionalized silica as a heterogeneous recyclable catalyst . Tetrahedron Letters. 2006, 93, (24), 8693-8697.